Sticking coefficients of deuterium from are quantified on fusion relevant plasma sprayed tungsten and carbon fibre composite in the incident energy range from about 0–100 eV. The samples that were cut from ASDEX-Upgrade tiles are exposed to a beam of of specific incident energy, Einc, in the tandem mass spectrometer BESTOF in Innsbruck. Nuclear reaction analysis is performed ex-situ at IPP Garching for the quantification of deuterium content. The deuterium content difference measured on a spot before and after ion-beam exposure of the sample is assigned to the above mentioned species of hydrocarbon molecules sticking on the surface, allowing the calculation of the sticking probability of a specific deuterated molecular ion. The sticking coefficient, S, is found to depend on the incident energy and shows a maximum of about S ∼ 0.4 around Einc = 30 eV on CFC and about S ∼ 0.1 near Einc = 20 eV in case of PSW.